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In this installment on the history of atom theory, physics professor (and my dad) Dean Zollman discusses how Werner Heisenberg—he of the Uncertainty Principle—decided to take a mathematical approach to something he couldn’t observe. For those who need a refresher, Heisenberg’s Uncertainty Principle is that we cannot know both the position and momentum of a particle precisely, and that the more we know about one, the less we know about the other.—Kim

By Dean Zollman

Dean ZollmanIn the last post, I discussed an experimental confirmation of Louis de Broglie’s hypothesis that matter could behave as waves do. In that case, Clinton Davisson and Lester Germer observed interference effects that could occur only if matter had wave-like behavior. In this post, we will back up in time just a little and consider the first of two theoretical developments that also occurred in the mid-1920s. The second approach will be discussed next time.

In 1925, Werner Heisenberg (1901-1976) was conducting research at the University of Goettingen in Germany. He was working under the direction of Max Born (1882-1970) and trying to resolve some of the mysteries that recent experimental discoveries had revealed. He had just spent about eight months working with Niels Bohr in Copenhagen. Thus, he was building on Bohr’s work and trying to find a fundamental basis to explain the Bohr Model of the Atom and the discrete spectrum of the hydrogen atom. Heisenberg had concluded that he needed to “reinterpret” classical mechanics in order to bring quantum ideas in to the picture.

Werner Heisenberg

Werner Heisenberg in about 1927

Heisenberg’s basic approach was to avoid ideas such as orbiting electron because they were not observable. Instead, he pursued a mathematical theory. At one point in a letter to Wolfgang Pauli (1900-1958), he stated, “My entire meager efforts go toward killing off and suitably replacing the concept of orbital paths that one cannot observe.”

To do so, he looked first at a situation that was simpler than an atom—a certain kind of oscillating object whose behavior was not quite periodic. Heisenberg and his colleagues at Goettingen made some progress. They were able to base their theory on a new set of mathematical operations. While this approach showed some promise, it did not involve Planck’s constant and thus did bring in the latest quantum interpretations.

Max Born

Max Born; in addition to being a Nobel laureate, he was Olivia Newton-John’s maternal grandfather

While working intensely on this issue, Heisenberg suffered an extreme attack of hay fever. He needed to get away from pollen, so on June 7, 1925, he left for the island of Helgoland. This German island in the North Sea has very little vegetation and therefore very little pollen. As he recovered from the hay fever, Heisenberg also had very little distractions. So, he was able to develop a mathematical approach to quantum physics.

When Heisenberg returned to Goettingen, he presented the ideas to Max Born and his young assistant Pascual Jordon (1902-1980). They recognized that Heisenberg’s formulation was quite similar to a relatively new mathematical concept called the matrix. So, they expanded the ideas to create a matrix approach to quantum physics.

Pascual Jordon

Pascual Jordon in the 1920s (unknown photographer, Mondadori Publishers)

While Heisenberg’s matrix mechanics worked to obtain observable results, it was very difficult to use to complete calculations. For example, Wolfgang Pauli obtained the energy levels in the hydrogen atom using matrices and thus connected it back to Bohr’s ideas and the spectrum of hydrogen. However, it took him 40 pages of calculations to get to a result that could be observed in an experiment.

One of Heisenberg’s biographers, David Cassidy, states, “The new mechanics was (and is) nearly incomprehensible to the technically uninitiated.”

Unfortunately, that statement does seem to be true. Part of the reason is that matrix mechanics, as it became to be known, is not easily visualized. During the years that I have been teaching quantum physics to non-science students, I have not found an acceptable way to present this approach to students who have not studied the detail of matrix algebra.

Fortunately, a different method that was developed about the same time is more easily visualized. We will look at that approach and learn about Erwin Schroedinger in the next post and the rivalry that developed between Heisenberg and Schroedinger.

Public domain images via Wikimedia Commons.

Dean Zollman is university distinguished professor of physics at Kansas State University, where he has been a faculty member for more than 40 years. During his career he has received four major awards — the American Association of Physics Teachers’ Oersted Medal (2014), the National Science Foundation Director’s Award for Distinguished Teacher Scholars (2004), the Carnegie Foundation for the Advancement of Teaching Doctoral University Professor of the Year (1996), and AAPT’s Robert A. Millikan Medal (1995). His present research concentrates on the teaching and learning of physics and on science teacher preparation.

Previously

What Are Things Made of? Depends on When You Ask.

Ancient Greeks Were the First to Hypothesize Atoms

The Poetry of Atoms

Atom Theory in Ancient India

Religion, Science Clashed over Atoms

Medieval Arabic Scholarship Might Have Preserved Scientific Knowledge

Rediscovering a Roman Poet – and Atom Theory – Centuries Later

Reconciling Atom Theory with Religion

Did Atom Theory Play a Role in Galileo’s Trouble with the Inquisition?

Did Gifted Scientist’s Belief in Atoms Led to His Obscurity?

Does Atom Theory Apply to the Earthly and the Divine?

A Duchess Inspired by Atoms

Separating Atoms from Atheism

Isaac Newton: 300 Years Ahead of His Time

Issac Newton and the Philosopher’s Stone

When Chemistry and Physics Split

Redefining Elements

Mme Lavoisier: Partner in Science, Partner in Life

With Atoms, Proportionality and Simplicity Rule

Despite Evidence of Atoms, 19th Century Skeptics Didn’t Budge

Mission of the First International Scientific Conference: Clear up Confusion

Rivalry over the First Periodic Table

The Puzzle of Dark Lines amid Rainbow Colors

The Colorful Signature of Each Element

Light Waves by the Numbers

Even Scientific Dead Ends Can Contribute to Knowledge

Discovery of the Electron Took Decades and Multiple Scientists

‘Wonders of the X-ray’

The Accidental Discovery of Radioactivity

Marie Curie: A Determined Scientist

Pierre and Marie Curie Extract Radium – and Pay a High Price

Scientists Delve into Radioactivity and Make Their Own Discoveries

The First Attempts to Visualize Atoms

Did Busy Work Lead to Models for Atoms?

Why Does Ice Melt? The Answer Lies in Physics.

Einstein Explains How a Dim Light Can Release More Energy Than a Bright One

How Bohr’s Famous Model of the Atom Was Created

Bohr’s Model of the Atom Answers Fundamental Questions – but Raises More

Bohr’s Model of the Atom Draws Critics

‘A First Feeble Ray of Light’ to Explain Electrons’ Orbits

Two Labs across the Atlantic Prove That Electrons Behave Like Waves

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